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Dry lubricant : ウィキペディア英語版
Dry lubricant

Dry lubricants or solid lubricants are materials which despite being in the solid phase, are able to reduce friction between two surfaces sliding against each other without the need for a liquid oil medium.〔Thorsten Bartels et al. "Lubricants and Lubrication" in Ullmann's Encyclopedia of Industrial Chemistry, 2005, Weinheim. 〕
The two main dry lubricants are graphite and molybdenum disulfide. They offer lubrication at temperatures higher than liquid and oil-based lubricants operate. Dry lubricants are often used in applications such as locks or dry lubricated bearings. Such materials can operate up to 350 °C (662 °F) in oxidizing environments and even higher in reducing / non-oxidizing environments (molybdenum disulfide up to 1100 °C, 2012 °F). The low-friction characteristics of most dry lubricants are attributed to a layered structure on the molecular level with weak bonding between layers. Such layers are able to slide relative to each other with minimal applied force, thus giving them their low friction properties.
However, a layered crystal structure alone is not necessarily sufficient for lubrication. In fact, there are also some solids with non-lamellar structures that function well as dry lubricants in some applications. These include certain soft metals (indium, lead, silver, tin), polytetrafluroethylene, some solid oxides, rare-earth fluorides, and even diamond.
Limited interest has been shown in low friction properties of compacted oxide glaze layers formed at several hundred degrees Celsius in metallic sliding systems. However, practical use is still many years away due to their physically unstable nature.
The four most commonly used solid lubricants are:
# Graphite. Used in air compressors, food industry, railway track joints, open gear, ball bearings, machine-shop works, etc. It is also very common for lubricating locks, since a liquid lubricant allows particles to get stuck in the lock worsening the problem.
# Molybdenum disulfide (MoS2). Used in CV joints and space vehicles. Does lubricate in vacuum.
# Hexagonal boron nitride. Used in space vehicles. Also called "white graphite."
# Tungsten disulfide. Similar usage as molybdenum disulfide, but due to the high cost only found in some dry lubricated bearings.
Graphite and molybdenum disulfide are the predominant materials used as dry lubricants.
==Structure-function relationship==
The lubricity of many solids is attributable to a lamellar structure. The lamellae orient parallel to the surface in the direction of motion and slide easily over each other resulting in low friction and preventing contact between sliding components even under high loads. Large particles perform best on rough surfaces at low speed, finer particles on smoother surfaces and at higher speeds. These materials may also be added in the form of dry powder to liquid lubricants to modify or enhance their properties.
Other components that are useful solid lubricants include boron nitride, polytetrafluorethylene (PTFE), talc, calcium fluoride, cerium fluoride, and tungsten disulfide.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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